Zinc-based flow batteries have attracted tremendous attention owing to their outstanding advantages of high theoretical gravimetric capacity, low electrochemical potential, rich abundance, and lo.
How do alkaline zinc-iron flow batteries work?
These batteries can work in a wide range of pH by adopting different varieties of iron couples. An alkaline zinc-iron flow battery usually has a high open-circuit voltage and a long life cycle performance using porous electrode and membrane.
What technological progress has been made in zinc-iron flow batteries?
Significant technological progress has been made in zinc-iron flow batteries in recent years. Numerous energy storage power stations have been built worldwide using zinc-iron flow battery technology. This review first introduces the developing history.
Are zinc-iron flow batteries suitable for grid-scale energy storage?
Among which, zinc-iron (Zn/Fe) flow batteries show great promise for grid-scale energy storage. However, they still face challenges associated with the corrosive and environmental pollution of acid and alkaline electrolytes, hydrolysis reactions of iron species, poor reversibility and stability of Zn/Zn 2+ redox couple.
What is the difference between acidic and neutral zinc-iron flow batteries?
In an acidic zinc-iron flow battery, the iron ions in the positive side have good solubility and reversible chemical stability, while zinc in the negative side is greatly affected by the pH. The neutral zinc-iron flow battery has attracted more attention due to its mild condition and low cost using a porous membrane.
Are zinc-iron flow batteries safe?
Zinc-iron flow batteries are one of the most promising electrochemical energy storage technologies because of their safety, stability, and low cost. This review discusses the current situations and problems of zinc-iron flow batteries. These batteries can work in a wide range of pH by adopting different varieties of iron couples.
Xie, C. et al. Highly stable zinc–iodine single flow batteries with super high energy density for stationary energy storage. Energy Environ. Sci. 12, 1834–1839 (2019). Xie, C. et al. A highly reversible neutral zinc/manganese battery for stationary energy storage.